[mer,trans-(NN ' N)RuCl2(NC5H5)]center dot C7H8 {NN ' N=2,6-bis-[(dimethylamino)methyl]pyridine}

Authors
Back, S Rheinwald, G del Rio, I van Koten, G Lang, H
Citation
S. Back et al., [mer,trans-(NN ' N)RuCl2(NC5H5)]center dot C7H8 {NN ' N=2,6-bis-[(dimethylamino)methyl]pyridine}, ACT CRYST E, 57, 2001, pp. m444-m445
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
10
Pages
m444 - m445
Database
ISI
SICI code
1600-5368(200110)57:<m444:['NDC{>2.0.ZU;2-Y
Abstract
The title compound, mer,trans-{2,6-bis[(dimethylamino)methyl]pyridine}dichl oropyridineruthenium(II) toluene solvate, [RuCl2 (C11H19N3)(C5H5N)] . C7H8, has metal-ligand dimensions of Ru-N-py (NN'N) 1.962 (2) Angstrom, Ru-N(NN' N) 2.348 (3) Angstrom, Ru-N(NN'N) 2.251 (3) Angstrom, Ru-N-py 2.096 (2) Ang strom and Ru-Cl 2.3502 (7) or 2.3581 (7) Angstrom (py = pyridine, C5H5N). A ngles are N-py-Ru-N(NN'N) 178.37 (9)degrees, (NN'N)N-Ru- N(NN'N) 160.57 (9) degrees and Cl-Ru-Cl 177.19 (3)degrees.