Diaquabis(N,N-diethylnicotinamide)bis(2-hydroxybenzoato)zinc(II)

Citation
H. Necefoglu et al., Diaquabis(N,N-diethylnicotinamide)bis(2-hydroxybenzoato)zinc(II), ACT CRYST E, 57, 2001, pp. m462-m464
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
10
Pages
m462 - m464
Database
ISI
SICI code
1600-5368(200110)57:<m462:D>2.0.ZU;2-0
Abstract
The title compound, [Zn(C7H5O3)(2) (C10H14N2O)(2) (H2O)(2)], crystallizes a s centrosymmetric mononuclear molecules with octahedrally coordinated zinc, all pairs of equivalent ligands being mutually trans. Intramolecular hydro gen bonding links each aqua ligand and the hydroxy group of a 2-hydroxybenz oate ligand with the uncoordinated carboxylate O atom of the same carboxyla te ligand, lengthening this C-O bond so that it has almost the same length as that for the coordinated O atom. Intermolecular hydrogen bonding between aqua ligands and the carbonyl O atoms of N,N-diethylnicotinamide ligands l ink the molecules together into chains.