The title compound, [Zn(C7H5O3)(2) (C10H14N2O)(2) (H2O)(2)], crystallizes a
s centrosymmetric mononuclear molecules with octahedrally coordinated zinc,
all pairs of equivalent ligands being mutually trans. Intramolecular hydro
gen bonding links each aqua ligand and the hydroxy group of a 2-hydroxybenz
oate ligand with the uncoordinated carboxylate O atom of the same carboxyla
te ligand, lengthening this C-O bond so that it has almost the same length
as that for the coordinated O atom. Intermolecular hydrogen bonding between
aqua ligands and the carbonyl O atoms of N,N-diethylnicotinamide ligands l
ink the molecules together into chains.