In the title compound, C3H8NO2+.C4H3O4-, the fi-alanine molecule exists in
the cationic form with a positively charged amino group and an uncharged ca
rboxylic acid group. The maleic acid molecule exists in the mono-ionized st
ate. In the semi-maleate ion, the intramolecular hydrogen bond between atom
s O3 and O5 is found to be asymmetric. There are no direct hydrogen-bonded
interactions between the semi-maleate anions. The nature of interactions be
tween individual molecules is different from those observed in L-alaninium
maleate.