trans-tetraaquabis(pyridine-3-carboxylate-kappa N)-nickel(II)

Authors
Batten, SR Harris, AR
Citation
Sr. Batten et Ar. Harris, trans-tetraaquabis(pyridine-3-carboxylate-kappa N)-nickel(II), ACT CRYST E, 57, 2001, pp. M9-M11
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
1
Pages
M9 - M11
Database
ISI
SICI code
1600-5368(200101)57:<M9:TN>2.0.ZU;2-J
Abstract
The title complex, [Ni(C6H4NO2)(2) (H2O)(4)], consists of an Ni atom coordi nated to two trans pyridinecarboxylate ligands, coordinated through the N a toms, and four water ligands. The Ni atom lies on a site of 2/m symmetry, a nd the pyridinecarboxylate ligand lies on a mirror plane. Extensive interco mplex hydrogen bonding occurs between the water ligands and the carboxylate groups, resulting in a three-dimensional network.