[TcCl(CS)(dppe)(2)]center dot C6H6

Authors
Bryan, JC Burrell, AK Kubas, GJ
Citation
Jc. Bryan et al., [TcCl(CS)(dppe)(2)]center dot C6H6, ACT CRYST E, 57, 2001, pp. M23-M24
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
1
Pages
M23 - M24
Database
ISI
SICI code
1600-5368(200101)57:<M23:[DC>2.0.ZU;2-R
Abstract
The title compound, chlorobis[1,2-ethanediylbis(diphenylphosphine)-P,P'](th iocarbonyl-C)technetium benzene solvate, [TcCl(C46H42P4)(CS)] . C6H6, was o btained as one of two Tc-containing products isolated from the reaction bet ween CS2 and the electron-dfircient complex [TcCl\-th>(dppe)(2)], where dpp e is 1,2-ethanediylbis(diphenylphosphine). The structure exhibits an unusua lly short Tc-C distance [1.819 (6) Angstrom], suggesting some multiple-bond character.