Citation
M. Du et al., Redetermination of [bis(2-pyridyl)amine-N,N ']copper(II) diperchlorate, ACT CRYST E, 57, 2001, pp. M25-M27
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368
→ ACNP
Volume
57
Year of publication
2001
Part
1
Pages
M25 - M27
Database
ISI
SICI code
1600-5368(200101)57:<M25:RO['D>2.0.ZU;2-0
Abstract
In the crystal structure of the title complex, [Cu(C10H9N3)(2)](ClO4)(2), t
he Cu-II center is four-coordinated by the nitrogen donors of the pyridine
rings of the ligand, bis(2-pyridyl)amine. The crystal structure reveals tha
t the CuN4 coordination sphere has a distorted tetrahedral coordination geo
metry with a crystallographic C-2 axis through the Cu-II center. The perchl
orate anions link the complex cations to form a chain structure through C-H
. . .O close contacts and N-H . . .O hydrogen bonds.