Bis[hexaaquacerium(III)] tetraaquacopper(II) tetrasquarate dihydrate

Citation
Sw. Ng et al., Bis[hexaaquacerium(III)] tetraaquacopper(II) tetrasquarate dihydrate, ACT CRYST E, 57, 2001, pp. M28-M30
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
1
Pages
M28 - M30
Database
ISI
SICI code
1600-5368(200101)57:<M28:BTTD>2.0.ZU;2-Z
Abstract
The cerium ion in the title compound, [Ce(OH2)(6)](2) [Cu(OH2)(4)](C4O4)(4) . 2H(2)O, is nine-coordinate in a monocapped square-prismatic geometry. Th e squarate (3,4-dihydroxy-3-cyclobutene-1,2-dionate) group links the cerium and copper ions into a three-dimensional network structure.