Bis(N-cyclohexyl-N-ethyldithiocarbamato-S,S ')lead(II)

Authors
Baba, I Farina, Y Othman, AH Razak, IA Fun, HK Ng, SW
Citation
I. Baba et al., Bis(N-cyclohexyl-N-ethyldithiocarbamato-S,S ')lead(II), ACT CRYST E, 57, 2001, pp. M35-M36
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
1
Pages
M35 - M36
Database
ISI
SICI code
1600-5368(200101)57:<M35:B'>2.0.ZU;2-5
Abstract
The Pb atom in the title compound, [Pb(C9H16NS2)(2)], is chelated in an ani sobidentate manner by the dithiocarbamate group [Pb-S = 2.710 (2)/2.883(2) Angstrom and 2.700 (2)/2.841(2) Angstrom]. The four-coordinate geometry is raised to six through the involvement of the double-bonded S atoms of adjac ent dithiocarbamato groups; the Pb . . .S interactions [Pb . . .S = 3.457 ( 2) and 3.508 (2) Angstrom] result in a chain structure for the compound.