VOLATILE MIXED-LIGAND COMPLEXES OF BIS(DIISOBUTYLDITHIOCARBAMATO)ZINCWITH 1,10-PHENANTHROLINE, 2,2'-BIPYRIDYL, AND 4,4'-BIPYRIDYL - CRYSTAL AND MOLECULAR-STRUCTURE OF THE BINUCLEAR COMPLEX [ZN-2(C10H8N2)((I-C4H9)(2)NCS2)(4)]

Authors
ZEMSKOVA SM GLINSKAYA LA KLEVTSOVA RF DURASOV VB GROMILOV SA LARIONOV SV
Citation
Sm. Zemskova et al., VOLATILE MIXED-LIGAND COMPLEXES OF BIS(DIISOBUTYLDITHIOCARBAMATO)ZINCWITH 1,10-PHENANTHROLINE, 2,2'-BIPYRIDYL, AND 4,4'-BIPYRIDYL - CRYSTAL AND MOLECULAR-STRUCTURE OF THE BINUCLEAR COMPLEX [ZN-2(C10H8N2)((I-C4H9)(2)NCS2)(4)], Journal of structural chemistry, 37(6), 1996, pp. 941-947
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
37
Issue
6
Year of publication
1996
Pages
941 - 947
Database
ISI
SICI code
0022-4766(1996)37:6<941:VMCOB>2.0.ZU;2-8
Abstract
Mixed-ligand complexes ZnPhen(i-Bu(2)Dtc)(2), Zn(2,2'-Bipy)(i-Bu(2)Dtc )(2), and Zn-2(4,4'-Bipy),(i-Bu(2)Dtc)(4), where i-Bu(2)Dtc = (i-C4H9) (2)NCS2-, have been synthesized The structure of Zn-2(4,4'-Bipy)(i-Bu( 2)Dtc)(4) was determined by X-ray diffraction analysis; it consists of centrosymmetric binuclear molecules with trigonal-bipyramidal coordin ation of the central Zn atom. When heated in vacuum, the compounds qua ntitatively sublimate or evaporate. Thermal decomposition of the compo unds in air (350 degrees C) gives alpha-ZnS.