We have successfully prepared highly c-axis-textured LiNbO3 films on hydrog
en-terminated Si (111) substrate using sol-gel spin-coating and rapid therm
al annealing. These highly c-axis-textured films were obtained with a prehe
ating at 300 degreesC for 15 min followed by a rapid thermal annealing at 5
00-700 degreesC for 120 s. The c-axis orientation of the LiNbO3 film is due
to a weak effect caused by the 3-fold symmetry match between the film and
the Si (111) substrate. The c-axis orientation of LiNbO3 films is very usef
ul in integrated optics devices and metal-ferroelectric-semiconductor nonvo
latile memory applications.