Microstructure of titanium dioxide (TiO2) thin films grown in the atomic la
yer deposition (ALD) process from titanium ethoxide (Ti(OCH2CH3)(4)) and wa
ter (H2O) vapor was studied. It was revealed that formation of crystalline
(anatase) phase in the films at 200 degreesC and higher substrate temperatu
res resulted in considerable surface roughening and increase in the growth
rate. The effect most markedly contributed to the film growth at 200 degree
sC. At this temperature, the average growth rate increased 1.4 times with t
he increase of film thickness from about 100 to 280 nm. (C) 2001 Elsevier S
cience B.V. All rights reserved.