Electron spin resonance (ESR) can be sued to determine the thermal history
of charred organic material. Maize seeds were heated under controlled condi
tions in order to produce calibration curves relating g-values (the rate of
electron splitting) and spin intensities (the number of spin centres) to h
eating temperatures, times and conditions. These experiments reproduced res
ults that had been previously obtained by other laboratories, with some min
or exceptions. The calibration curves were then used to reconstruct the the
rmal histories of charred maize kernels from several prehistoric sites in e
astern North America. At these sties, the differing thermal histories of ma
ize kernels are correlated with depositional contexts.