Interpenetrating polymer networks based on polyol modified castor oil polyurethane and poly (2-hydroxyethylmethacrylate): Synthesis, chemical, mechanical and thermal properties
K. Prashantha et al., Interpenetrating polymer networks based on polyol modified castor oil polyurethane and poly (2-hydroxyethylmethacrylate): Synthesis, chemical, mechanical and thermal properties, B MATER SCI, 24(5), 2001, pp. 535-538
Interpenetrating polymer networks (IPNs) of glycerol modified castor oil po
lyurethane (GC-PU) and poly [2-hydroxyethylmethacrylate] (PHEMA) were synth
esized using benzoyl peroxide as initiator and N,N-methylene bis acrylamide
as crosslinker. GC-PU/PHEMA interpenetrating polymer networks were obtaine
d by transfer moulding. These were characterized with respect to their resi
stance to chemical reagents and mechanical properties such as tensile stren
gth, per cent elongation and shore A hardness. Differential scanning calori
metry (DSC) and thermogravimetric analysis (TGA) were undertaken for therma
l characterization. The changes in NCO/OH ratio and GC-PU/PHEMA composition
on the properties of the IPNs were studied.