Gas chromatographic behaviour of urea herbicides

Gas chromatographic conditions for determining eight phenylurea (chlortolur on, diuron, fluometuron, isoproturon, linuron, metabenzthiazuron, metobromu ron and monuron) and one sulfonylurea (chlorsulfuron) herbicides were asses sed. Degradation products of the herbicides formed in the injector were use d for identification. Most phenylureas formed their respective carbamic aci d methyl esters, metabenzthiazuron formed an aminobenzothiazol and chlorsul furon formed an aminotriazine plus a phenylsulfonamide. On-column injection of standards using a BP10 capillary column was evaluate d to identify the chromatographic behaviour. Detection limits ranged from 0 .05 ng for chlorsulfuron to 3 ng for monuron with the NPD and, from 0.01 ng for chlorsulfuron to 5 ng for metabenzthiazuron with the ECD. The RSDs (n = 4) were lower than 4% at the 12 - 25 ng level. The method was applied to the analysis of surface waters extracted with C18 Empore disks with recoveries higher than 85%. Each herbicide could be dete rmined in water down to 0.1 mug . L-1. Chlortoluron was found (11.4 mug . L -1) in a water sample and its presence was confirmed by gas chromatography- mass spectrometry.