AN IMPROVED OXIDATION METHOD FOR THE SYNTHESIS OF AZODICARBONYL COMPOUNDS

Authors
STARR JT RAI GS DANG H MCNELIS BJ
Citation
Jt. Starr et al., AN IMPROVED OXIDATION METHOD FOR THE SYNTHESIS OF AZODICARBONYL COMPOUNDS, Synthetic communications, 27(18), 1997, pp. 3197-3200
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
18
Year of publication
1997
Pages
3197 - 3200
Database
ISI
SICI code
0039-7911(1997)27:18<3197:AIOMFT>2.0.ZU;2-A
Abstract
Five representative hydrate compounds have been oxidized in high yield using Br-2 and pyridine. Yields range from 80% to 93%. For the synthe sis of dibenzyl azodicarboxylate, this process produced analytically p ure material directly from the reaction mixture.