Low-temperature synthesis of diamminesodium(1+) triamminesodium(1+) trithioantimonate (3-) ammoniate (1 : 2 : 1 : 2) ([Na(NH3)(3)](2)[Na(NH3)(2)]SbS3center dot 2 NH3), a solvated neutral sodium trithioantimonate(3-) (3 : 1)Na3SbS3) ion complex

Authors
Korber, N Richter, F
Citation
N. Korber et F. Richter, Low-temperature synthesis of diamminesodium(1+) triamminesodium(1+) trithioantimonate (3-) ammoniate (1 : 2 : 1 : 2) ([Na(NH3)(3)](2)[Na(NH3)(2)]SbS3center dot 2 NH3), a solvated neutral sodium trithioantimonate(3-) (3 : 1)Na3SbS3) ion complex, HELV CHIM A, 84(8), 2001, pp. 2368-2372
Citations number
14
Categorie Soggetti
Chemistry & Analysis",Chemistry
Journal title
HELVETICA CHIMICA ACTA
ISSN journal
0018019X → ACNP
Volume
84
Issue
8
Year of publication
2001
Pages
2368 - 2372
Database
ISI
SICI code
0018-019X(2001)84:8<2368:LSODTT>2.0.ZU;2-F
Abstract
A solution of sodium in liquid ammonia reacts with Sb2S3 to form large colo rless crystals of the composition Na3SbS3. 10 NH3. The trigonal-pyramidal S bS33- anion is ion-paired with three Na+ counter ions, the coordination sph eres of which are completed by eight ammine ligands. The resulting neutral [Na(NH3)(3)](2)-[Na(NH3)(2)]SbS3 Molecules crystallize together with two am monia molecules of solvation in the space group P2(1)/c (a = 9.828(2), b = 6.0702(4), c = 33.4377(6) Angstrom, beta = 91.362(7)degrees, V= 1994.2(5) A ngstrom (3), Z = 4).