The avalanche multiplication characteristics of Al0.8Ga0.2As have been inve
stigated in a series of p-i-n and n-i-p diodes with i-region widths, w, var
ying from 1 mum to 0.025 mum. The electron ionization coefficient, alpha, i
s found to be consistently higher than the hole ionization coefficient, bet
a, over the entire range of electric fields investigated. By contrast with
AlxGa1-xAs (x less than or equal to 0.6) a significant difference between t
he electron and hole initiated multiplication characteristics of very thin
Al0.8Ga0.2As diodes (w = 0.025 mum) was observed. Dead space effects in the
diodes with w less than or equal to 0.1 mum were found to reduce the multi
plication at low bias below the values predicted from bulk ionization coeff
icients. Effective alpha and beta that are independent of w have been deduc
ed from measurements and are able to reproduce accurately the multiplicatio
n characteristics of diodes with w greater than or equal to 0.1 mum and bre
akdown voltages of all diodes with good accuracy. By performing a simple co
rrection for the dead space, the multiplication characteristics of even thi
nner diodes were also predicted with reasonable accuracy.