Citation
M. Mach et S. Jarosz, Reaction of sugar phosphonates with sucrose aldehydes. Synthesis of higheranalogs of sucrose, J CARB CHEM, 20(5), 2001, pp. 411-424
Citations number
15
Categorie Soggetti
Chemistry & Analysis
Journal title
JOURNAL OF CARBOHYDRATE CHEMISTRY
ISSN journal
07328303
→ ACNP
Volume
20
Issue
5
Year of publication
2001
Pages
411 - 424
Database
ISI
SICI code
0732-8303(2001)20:5<411:ROSPWS>2.0.ZU;2-X
Abstract
The Horner-Emmons reaction between sugar phosphonates Sug-C(O)CH2 P(O)(OMe)
(2) and aldehydes derived from sucrose afforded precursors of higher analog
s of the general formula Sug-C(O)CH==CH-Suc. An example of the functionaliz
ation of the internal three-carbon saccharide connecting unit is provided.