A mathematics model is proposal for simulating desulfurization process in a
CaO activation reactor of a limestone injection FGD system. The effective
factors, including particle motion, water evaporation, particle impact, and
aqueous sorbent reaction, have been considered in this model. By use of ca
lculating results and experimental results from a 3000 N .m(3)/h pilot plan
t experimental system of CaO activation reactor, the effect of flue gas tem
perature, particle size, water injection and Ca/S molar ratio on desulfuriz
ation efficiency is investigated in detail. It is found that desulfurizatio
n efficiency rises with the increase of Ca/S molar ratio, the amount of wat
er injection and the decrease of particle size, flue gas temperature. A met
hod to improve desulfurization efficiency in the CaO activation reactor is
also given in this paper. The above results are a help for semi-dry FGD sys
tem design.