Oscillatory driven cavity with an air/water interface and an insoluble monolayer: Surface viscosity effects

Citation
Jm. Lopez et Ah. Hirsa, Oscillatory driven cavity with an air/water interface and an insoluble monolayer: Surface viscosity effects, J COLL I SC, 242(1), 2001, pp. 1-5
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF COLLOID AND INTERFACE SCIENCE
ISSN journal
00219797 → ACNP
Volume
242
Issue
1
Year of publication
2001
Pages
1 - 5
Database
ISI
SICI code
0021-9797(20011001)242:1<1:ODCWAA>2.0.ZU;2-J
Abstract
Flow in a planar cavity bounded by stationary side walls, a flat gas/liquid interface covered by an insoluble monolayer, and driven by sinusoidal moti on of the floor is examined numerically. Navier-Stokes computations with th e Boussinesq-Scriven surface model are presented utilizing the equation-of- state measured for a vitamin KI monolayer on the air/water interface. The r esults identify a range of initial surfactant concentration for which the s urface velocity is sensitive to the surface viscosity B (sum of surface she ar and dilatational viscosities) down to 10(-2) surface Poise. Thus, the st udy suggests a practical method for determining surface viscosities consist ing of the measurement of the motion of a tracer particle on the interface and comparisons with numerical computations at various values of B. (C) 200 1 Academic Press.