Evidence for the anchoring of 2-amino-3-methyl-1-butanol at the surface ofNiB2 agglomerate by inelastic neutron spectroscopy

Authors
Molvinger, K Court, J Jobic, H
Citation
K. Molvinger et al., Evidence for the anchoring of 2-amino-3-methyl-1-butanol at the surface ofNiB2 agglomerate by inelastic neutron spectroscopy, J MOL CAT A, 174(1-2), 2001, pp. 245-248
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169 → ACNP
Volume
174
Issue
1-2
Year of publication
2001
Pages
245 - 248
Database
ISI
SICI code
1381-1169(20011001)174:1-2<245:EFTAO2>2.0.ZU;2-H
Abstract
We have obtained by inelastic neutron spectroscopy physico-chemical evidenc e of the anchoring of 2-amino-3-methyl-1-butanol (AMB) on a metallic aggreg ate (NiB2). In the reduction of beta -fluoroacetophenone with borane complex, this hete rogeneous catalyst and the homogeneous catalyst prepared from AMB and boran e behave similarly. (C) 2001 Elsevier Science B.V. All rights reserved.