Manganese(III) acetate oxidation of some ketones in the presence of 3-chloropropionic acid and theoretical investigation of the products

Authors
Akdag, A Tarhan, O Turker, L
Citation
A. Akdag et al., Manganese(III) acetate oxidation of some ketones in the presence of 3-chloropropionic acid and theoretical investigation of the products, J MOL ST-TH, 571, 2001, pp. 201-206
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM
ISSN journal
01661280 → ACNP
Volume
571
Year of publication
2001
Pages
201 - 206
Database
ISI
SICI code
0166-1280(20010827)571:<201:MAOOSK>2.0.ZU;2-O
Abstract
Manganese(III) acetate oxidation of some ketones in the presence of 3-chlor opropionic acid was carried out. The products were characterized. The exper imental results were compared with the theoretical ones which was based on AM1 (UHF) type semi-empirical calculations. The theoretical results disfavo r any mechanism solely based on radical stability involving radicals origin ating from the reactants. (C) 2001 Elsevier Science B.V. All rights reserve d.