Determination of the vapor-liquid critical point from the short-time dynamics

Citation
Sy. Huang et al., Determination of the vapor-liquid critical point from the short-time dynamics, MOD PHY L B, 15(12-13), 2001, pp. 369-374
Citations number
32
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
MODERN PHYSICS LETTERS B
ISSN journal
02179849 → ACNP
Volume
15
Issue
12-13
Year of publication
2001
Pages
369 - 374
Database
ISI
SICI code
0217-9849(20010610)15:12-13<369:DOTVCP>2.0.ZU;2-K
Abstract
Considering the average potential energy per particle as the parameter, we investigate the early-time dynamics of vapor-liquid transition in the criti cal region for 2D Lennard-Jones fluids by using NVT molecular dynamics simu lations. The results verify the existence of short-time dynamic scaling in the fluid systems and show that the critical point T can be determined by t he universal short-time behavior. The obtained value of T-C = 0.540 from th e short-time dynamics is very close to the value of 0.533 from the Monte Ca rlo simulations in the equilibrium state of the systems.