The Cu-Nb alloy films with positive heat of mixing were prepared by ion-bea
m-assisted deposition (IBAD) technique. A new Nb-rich fec phase and an amor
phous phase, with composition range around 65-75%, Nb fraction, were obtain
ed in Cu-Nb films deposited under Ar+ ion bombardments with energy below 7
keV. The supersaturated bee phase was also formed in Cu20Nb80 films by IBAD
. The formation mechanism of metastable phases in Cu-Nb system is discussed
in terms of the procedure far from equilibrium and compared with that in F
e-Zr system by IBAD, (C) 2001 Elsevier Science B.V. All rights reserved.