Classic hydrodynamic wetting theory leads to an (approximately) linear rela
tionship between capillary force and spreading speed. When substrate/liquid
interfacial tension, gamma (SL), varies during spreading, due to reactivit
y, molecular relaxation or the diffusion of contaminants, behaviour can be
considerably modified. If gamma (SL) increases with time, drop shrinking (a
nd/or spontaneous motion) may be expected.