Hydrosilylation of carbonyl compounds using a PhSeSiMe3/Bu3SnH/AIBN system

Authors
Nishiyama, Y Kajimoto, H Kotani, K Sonoda, N
Citation
Y. Nishiyama et al., Hydrosilylation of carbonyl compounds using a PhSeSiMe3/Bu3SnH/AIBN system, ORG LETT, 3(20), 2001, pp. 3087-3089
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
3
Issue
20
Year of publication
2001
Pages
3087 - 3089
Database
ISI
SICI code
1523-7060(20011004)3:20<3087:HOCCUA>2.0.ZU;2-1
Abstract
[GRAPHICS] When carbonyl compounds were allowed to react with phenyl trimethylsilyl se lenide and tributylstannyl hydride in the presence of a catalytic amount of AIBN as a radical initiator, the hydrosilylation of the carbonyl compounds efficiently proceeded to give the corresponding silyl ethers in moderate t o good yields.