Synthesis and structure of the octanuclear manganese(II) cage [(eta-Cp)Mn{2-NH(4,6-Me(2)pm)center dot Mn{2-N(4,6-Me2Pm)}](4) (Cp = C5H5, pm = pyrimidine)

Authors
Aluarez, CS Bond, AD Harron, EA Layfield, RA McAllister, JA Pask, CM Rawson, JM Wright, DS
Citation
Cs. Aluarez et al., Synthesis and structure of the octanuclear manganese(II) cage [(eta-Cp)Mn{2-NH(4,6-Me(2)pm)center dot Mn{2-N(4,6-Me2Pm)}](4) (Cp = C5H5, pm = pyrimidine), ORGANOMETAL, 20(20), 2001, pp. 4135-4137
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
20
Year of publication
2001
Pages
4135 - 4137
Database
ISI
SICI code
0276-7333(20011001)20:20<4135:SASOTO>2.0.ZU;2-Q
Abstract
The 1:1 reaction of 2-NH2(4,6-Me(2)pm) with Cp2Mn in thf gives the novel he teroleptic imido / amido, Mn(II) cage [(eta -Cp)Mn{2-NH(4,6-Me(2)pm)}. Mn{2 -N(4,6-Me(2)pm)}](4) (1), composed of a central Mn(II) imido, [Mn-4{2-N(4,6 -Me(2)pm)}(4)] core coordinated at the periphery by four [(eta -Cp)Mn{2-NH( 4,6-Me(2)pm)}] monomer units.