An easy synthetic route to heteroleptic samarium monoalkoxides for ring-opening polymerization initiators. Molecular structures of [(C(5)Hi-Pr-4)SmI(THF)(2)](2), SMI(2)Ot-Bu(THF)(4), and (C4Me4P)(2)SmOt-Bu(THF)

Authors
Barbier-Baudry, D Heiner, S Kubicki, MM Vigier, E Visseaux, M Hafid, A
Citation
D. Barbier-baudry et al., An easy synthetic route to heteroleptic samarium monoalkoxides for ring-opening polymerization initiators. Molecular structures of [(C(5)Hi-Pr-4)SmI(THF)(2)](2), SMI(2)Ot-Bu(THF)(4), and (C4Me4P)(2)SmOt-Bu(THF), ORGANOMETAL, 20(20), 2001, pp. 4207-4210
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
20
Year of publication
2001
Pages
4207 - 4210
Database
ISI
SICI code
0276-7333(20011001)20:20<4207:AESRTH>2.0.ZU;2-D
Abstract
Samarium(III) monoalkoxides bearing two, one, or no cyclopentadienyl type s pectator ligands are easily synthesized by monoelectronic oxidation with te rt-butylperoxide of the corresponding samarium(II) precursors. These monoal koxides are single-site initiators for ring-opening polymerization.