Modern digital cross-correlators permit the simultaneous measurement of all
four Stokes parameters. However, the results must be calibrated to correct
for the polarization transfer function of the receiving system. The transf
er function for any device can be expressed by its Mueller matrix. We expre
ss the matrix elements in terms of fundamental system parameters that descr
ibe the voltage transfer functions (known as the Jones matrix) of the vario
us system devices in physical terms and thus provide a means for comparing
with engineering calculations and investigating the effects of design chang
es. We describe how to determine these parameters with astronomical observa
tions. We illustrate the method by applying it to some of the receivers at
the Arecibo Observatory.