Thermochemistry of aniline solution in binary mixtures water-aprotic solvent

Authors
Batov, DV Antonova, OA Korolev, VP
Citation
Dv. Batov et al., Thermochemistry of aniline solution in binary mixtures water-aprotic solvent, RUSS J G CH, 71(5), 2001, pp. 689-695
Citations number
30
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
5
Year of publication
2001
Pages
689 - 695
Database
ISI
SICI code
1070-3632(200105)71:5<689:TOASIB>2.0.ZU;2-W
Abstract
Enthalpies of aniline solution in mixed solvents water-1,4-dioxane, water-a cetone, and water-dimethyl sulfoxide at 25 degreesC were determined within entire ranges of their compositions. The enthalpies of its solvation and tr ansfer from water into mixed solvents, and also contributions of hydrocarbo n radicals and functional groups to these quantities were calculated. Effec ts of composition and properties of the mixtures on the aniline thermochemi cal characteristics in solutions were considered.