Synthesis of cyclohexylideneacetonitrile on zeolites

Authors
Kozlov, NG Rusak, MF
Citation
Ng. Kozlov et Mf. Rusak, Synthesis of cyclohexylideneacetonitrile on zeolites, RUSS J G CH, 71(5), 2001, pp. 756-758
Citations number
8
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
71
Issue
5
Year of publication
2001
Pages
756 - 758
Database
ISI
SICI code
1070-3632(200105)71:5<756:SOCOZ>2.0.ZU;2-N
Abstract
Condensation of cyclohexanone with acetonitrile oil zeolites with different carcass structures was studied. The highest yield of cyclohexylideneaceton itrile (80 wt %) at a 98% selectivity of tile process was attained with NaX zeolite containing 0.5 wt % KOH. Factors responsible for different catalyt ic activities and selectivities of zeolites are discussed.