Oxidation of coordinated nitroso into nitrito group in palladium complexes: Synthesis and molecular structure of (Ph4P)(2)[Pd-2(NO2)(2)Cl-4]

Authors
Boganova, LI Pashchenko, DV Churakov, AV Minaeva, NA Stromnova, TA
Citation
Li. Boganova et al., Oxidation of coordinated nitroso into nitrito group in palladium complexes: Synthesis and molecular structure of (Ph4P)(2)[Pd-2(NO2)(2)Cl-4], RUSS J IN C, 46(9), 2001, pp. 1339-1341
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
9
Year of publication
2001
Pages
1339 - 1341
Database
ISI
SICI code
0036-0236(200109)46:9<1339:OOCNIN>2.0.ZU;2-1
Abstract
An ionic palladium chloro nitroso complexes were synthesized; their oxidati on by atmospheric oxygen produces nitrito complexes. The structure of the c omplex (Ph4P)(2)[Pd-2(NO2)(2)Cl-4] (I) was studied by X-ray crystallography : a = 10.418(3) Angstrom, b = 10.893(3) Angstrom, c = 10.982(4) Angstrom, a lpha = 78.72(3)degrees, beta = 71.99(3)degrees, gamma = 80.04(2)degrees, V = 1153.8(6) Angstrom (3), space group P (1) over bar, Z = 1, d(calc) = 1.62 0 g/cm(3).