Kk. Palkina et al., Synthesis and structure of lanthanum oxalate crystal hydrate La-2(C2O4)(3)center dot 9.2H(2)O, RUSS J IN C, 46(9), 2001, pp. 1348-1351
Results of the synthesis and X-ray structure determination for La-2(C2O4)(3
) . 9.2H(2)O are reported. The crystals are monoclinic, space group P2(1)/a
, a = 10.460(2) Angstrom, b = 9.590(2) Angstrom, c = 11.358(2) Angstrom, be
ta = 114.36(03)degrees, V = 1308(1) Angstrom (3), Z = 2, rho (calc) = 2.23
g/cm(3). In the layered structure, lanthanum atoms are linked by acetato br
idges. The coordination sphere of the La atom consists of six oxygen atoms
from three oxalato groups and three oxygen atoms of water molecules. The la
yers lie parallel to the xz plane. Four water molecules whose oxygen atoms
do not coordinate metal atoms are disordered and arranged between the layer
s.