Ss. Rao et al., A PTC assisted thionation: Synthesis of 2H-1,4-benzoxazine-3(4H)-thiones &2H-1,4-benzothiazine-3(4H)-thiones, SYN COMMUN, 31(22), 2001, pp. 3469-3472
A facile method for the conversion of 2H-1,4-benzoxa/thiazine-3(4H)-ones to
their respective thiones under PTC (P2S5/K2CO3/TEBA) conditions is reporte
d.