Synthetic studies on the sarcodictyins: synthesis of fully functionalized cyclization precursors

Authors
Ceccarelli, SM Piarulli, U Gennari, C
Citation
Sm. Ceccarelli et al., Synthetic studies on the sarcodictyins: synthesis of fully functionalized cyclization precursors, TETRAHEDRON, 57(40), 2001, pp. 8531-8542
Citations number
51
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
57
Issue
40
Year of publication
2001
Pages
8531 - 8542
Database
ISI
SICI code
0040-4020(20011001)57:40<8531:SSOTSS>2.0.ZU;2-2
Abstract
A strategy featuring a key retrosynthetic disconnection at the C2-C3 positi on was applied to the total synthesis of the common diterpenoid tricyclic s keleton of sarcodictyins and eleutherobin. Fully functionalized cyclization precursors were accessed via a brief and convergent route, making use of u nprecedented synthetic transformations. (C) 2001 Elsevier Science Ltd. All rights reserved.