Imino-Diels-Alder and imino-aldol reactions catalyzed by samarium diiodide

Authors
Collin, J Jaber, N Lannou, MI
Citation
J. Collin et al., Imino-Diels-Alder and imino-aldol reactions catalyzed by samarium diiodide, TETRAHEDR L, 42(42), 2001, pp. 7405-7407
Citations number
20
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
42
Year of publication
2001
Pages
7405 - 7407
Database
ISI
SICI code
0040-4039(20011015)42:42<7405:IAIRCB>2.0.ZU;2-K
Abstract
In the presence or a catalytic amount of samarium diiodide in methylene chl oride, aromatic imines react with Danishefsky diene to form tetrahydropyrid ine-4-ones in high yields. Under the same conditions, various imino-aldol r eactions afford beta -amino esters or beta -amino ketones. (C) 2001 Elsevie r Science Ltd. All rights reserved.