Regioselective radical elimination of o-(bromoaryl)sulfides

Authors
Kamimura, A Mitsudera, H
Citation
A. Kamimura et H. Mitsudera, Regioselective radical elimination of o-(bromoaryl)sulfides, TETRAHEDR L, 42(42), 2001, pp. 7457-7460
Citations number
32
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
42
Year of publication
2001
Pages
7457 - 7460
Database
ISI
SICI code
0040-4039(20011015)42:42<7457:RREOO>2.0.ZU;2-H
Abstract
Treatment of o-(bromophenyl)sulfides with Bu3SnH or (Bu,Sn), resulted in th e regioselective elimination of thiol to give internal or terminal alkenes, which depend on radical conditions initiated thermally or photochemically, respectively. (C) 2001 Elsevier Science Ltd. All rights reserved.