Fluorocarbon accelerated supported transformations (FAST) on REM resin

Authors
Morphy, JR Rankovic, Z York, M
Citation
Jr. Morphy et al., Fluorocarbon accelerated supported transformations (FAST) on REM resin, TETRAHEDR L, 42(42), 2001, pp. 7509-7511
Citations number
6
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
42
Issue
42
Year of publication
2001
Pages
7509 - 7511
Database
ISI
SICI code
0040-4039(20011015)42:42<7509:FAST(O>2.0.ZU;2-D
Abstract
The use of perfluorous organic solvents in the solid-phase synthesis of 3 d egrees amines on REM resin allows a large reduction in both reaction time a nd the amount of amine required for a successful Michael reaction. Yields o f products were typically at least three fold greater than those observed,v ith standard solvents under the same conditions. (C) 2001 Elsevier Science Ltd. All rights reserved.