Fluorothiolate-dithioacid complexes of ruthenium(III) and osmium(III): crystal structure of [Os(SC6F5)(2)(S2CNEt2)(PMe2Ph)(2)]

Authors
Arroyo, M Bernes, S Melendez, L Richards, RL Torrens, H
Citation
M. Arroyo et al., Fluorothiolate-dithioacid complexes of ruthenium(III) and osmium(III): crystal structure of [Os(SC6F5)(2)(S2CNEt2)(PMe2Ph)(2)], TRANSIT MET, 26(6), 2001, pp. 608-612
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
26
Issue
6
Year of publication
2001
Pages
608 - 612
Database
ISI
SICI code
0340-4285(2001)26:6<608:FCORAO>2.0.ZU;2-U
Abstract
Treatment of the coordinative unsaturated complexes [M(SRF)(3)(PMe2Ph)(2)] (M = Os or Ru; R-F = C6F5 or C6F4H-4) with M'S(2)Z (M' = Na, S(2)Z = S2CNEt 2; M' = K, S(2)Z = S2COEt) and [Os(SRF)(3)(PMe2Ph)(2)] (R-F = C6F5 or C6F4H -4) with M'S(2)Z [M' = Na; S(2)Z = S2P(OEt)(2)] in Me2CO solution, gave the paramagnetic Os-III and Ru-III derivatives, [M(SRF)(2)(S(2)Z)(PMe2Ph)(2)]. X-ray crystallography shows that [Os(SC6F5)(2)(S2CNEt2)(PMe2Ph)(2)] has an octahedral geometry with trans-fluorothiolates, cis-phosphines and a chela ting N,N-diethyldithiocarbamate ligand.