Pervaporation data of ethanolic solutions of linalool, in various oper
ating conditions, are presented to test the efficiency of the transfer
model based on the Thermodynamics of Irreversible Processes (TIP). Th
is approach leads to the calculation of the observed permeation flux b
y means of phenomenological coefficients which reflect coupling effect
s between each permeant and the membrane material, as well as the coup
ling effects between the permeants themselves. Experimental results al
low to estimate groups of phenomenological coefficients and the influe
nce of the operating conditions on them. This first presentation prove
s a good fitting of the theoretical description on the experimental re
sults and, particularly, the efficiency of this approach to account ea
sily for pervaporation of several permeants.