[{C8H12Rh}3(mu(3)-OH)(2)]SbF6: A new organometallic rhodium complex with Rh3O2 core

Authors
Kuhn, N Grathwohl, M Nachtigal, C Steimann, M Henkel, G
Citation
N. Kuhn et al., [{C8H12Rh}3(mu(3)-OH)(2)]SbF6: A new organometallic rhodium complex with Rh3O2 core, Z ANORG A C, 627(9), 2001, pp. 2039-2041
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
9
Year of publication
2001
Pages
2039 - 2041
Database
ISI
SICI code
0044-2313(200109)627:9<2039:[ANORC>2.0.ZU;2-E
Abstract
Crystals of C24H38F7O2Rh3Sb (3) obtained from the crystallisation of 2 from wet solvents consist of [{C8H12Rh}(3)(mu (3)-OH)(2)](+) cations connected with the SbF6- anions via hydrogen bonds. In the cations, the Rh-3 faces ar e bicapped by OH- ligands.