Layered structure of catena-poly[[bis[1-(2-azidoethyl)tetrazole-N-4]copper(II)]-di-mu-chloro]

Citation
Do. Ivashkevich et al., Layered structure of catena-poly[[bis[1-(2-azidoethyl)tetrazole-N-4]copper(II)]-di-mu-chloro], ACT CRYST E, 57, 2001, pp. M335-M337
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
ISSN journal
16005368 → ACNP
Volume
57
Year of publication
2001
Part
8
Pages
M335 - M337
Database
ISI
SICI code
1600-5368(200108)57:<M335:LSOC>2.0.ZU;2-Y
Abstract
In the title compound, [CuCl2(C3H5N7)(2)], the coordination polyhedron of t he Cu atom is an elongated square bipyramid with (1) over bar site symmetry . The equatorial positions are occupied by the two Cl atoms with Cu-Cl dist ances of 2.288 (1) Angstrom and two azidoethyltetrazole ligands with Cu-N d istances of 1.999 (2) Angstrom. Two Cl atoms in axial positions are 2.956 ( 1) Angstrom distant from the Cu atom. The Cl atoms play the role of nonsymm etrical bridges responsible for formation of layers parallel to the bc plan e.