The tribological behavior of platelet and nested colloidal particles of tun
gsten disulfide was Studied using the surface forces apparatus, atomic forc
e microscopy, lateral force microscopy, and Auger spectroscopy. Shear-induc
ed material transfer from the colloidal particles to the surfaces was shown
to be a dominant factor in the tribological behavior observed for both str
uctures. An ultrathin, ordered layer was observed when nested particles wer
e sheared, while WS2 platelets produced a rough and disordered transfer lay
er, with substantially inferior lubricating properties.