Capillary interactions at a water-air interface were used to align a two-in
ch glass wafer to a three-inch silicon wafer. Flat, smooth silica surfaces
were patterned with gold millimeter-scale borders enclosing micrometer-scal
e features. The gold features were rendered hydrophobic through the use of
self-assembled monolayers, the silica was wetted with water, and the wafers
were pressed together. The assembly snapped into alignment based upon the
minimization of the curvature of the meniscus formed at the water-air inter
face. The accuracy of this alignment was better than one micrometer. Gravit
ational energy was used to systematically study the alignment force as a fu
nction of pattern parameters. These data can be modelled by interfacial ene
rgy theory. These experiments identify a clear set of conditions necessary
for the use of this technique for high-precision alignment.