THERMODYNAMIC STUDY OF THE BINARY MIXTURE TRICHLOROMETHANE-1,2-EPOXYBUTANE

Authors
LUNELLI B FRANCESCONI R COMELLI F
Citation
B. Lunelli et al., THERMODYNAMIC STUDY OF THE BINARY MIXTURE TRICHLOROMETHANE-1,2-EPOXYBUTANE, Journal of the Chemical Society. Faraday transactions, 93(15), 1997, pp. 2527-2532
Citations number
43
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Journal of the Chemical Society. Faraday transactions → ACNP
ISSN journal
09565000
Volume
93
Issue
15
Year of publication
1997
Pages
2527 - 2532
Database
ISI
SICI code
0956-5000(1997)93:15<2527:TSOTBM>2.0.ZU;2-D
Abstract
A previously reported 'chemical' model proposes that most strongly non -ideal binary mixtures can be described as consisting of both simple c hemical species and their associates. FTIR spectroscopy indicates that the title mixture can be considered to consist mainly of CHCl3, C4H8O , CHCl3 . C4H8O, and (CHCl3)(2). Comparison between experimental exces s enthalpies and those calculated using the model indicates that such a composition provides a viable description of the mixture.