New C-substituted (1S,4S)-2,5-diazabicyclo[2.2.1]heptane derivatives. Preparation utilizing the directed metalation strategy. Application in enantioselective catalysis

Authors
Jordis, U Kesselgruber, M Nerdinger, S
Citation
U. Jordis et al., New C-substituted (1S,4S)-2,5-diazabicyclo[2.2.1]heptane derivatives. Preparation utilizing the directed metalation strategy. Application in enantioselective catalysis, ARKIVOC, 2, 2001, pp. 1149-1161
Citations number
29
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ARKIVOC → ACNP
Volume
2
Year of publication
2001
Part
2
Pages
1149 - 1161
Database
ISI
SICI code
Abstract
New C-substituted derivatives of (1S,4S)-2-methyl-2,5-diazabicyclo[2.2.1]he ptane were synthesized utilizing the directed metalation strategy. The abso lute configuration of the 3-substituted derivative rests on the comparison of the NMR spectra with a product of proven configurational assignment by X -ray crystallographic analysis.