Lithium tri-sec-butylborodeuteride: a new reagent for the stereoselective deuterium addition to cyclohexanones with single chair conformations

Citation
P. Gartner et al., Lithium tri-sec-butylborodeuteride: a new reagent for the stereoselective deuterium addition to cyclohexanones with single chair conformations, ARKIVOC, 2, 2001, pp. 1162-1173
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
Volume
2
Year of publication
2001
Part
2
Pages
1162 - 1173
Database
ISI
SICI code
Abstract
The preparation and application of a new reagent for stereoselective deuter ium addition to substituted cyclohexanones is described affording cyclohexa nols with axial hydroxy group with high stereoselectivity. The results are compared with other established reduction methods.