Crystal structure and photo-reaction of a new coordination polymer: [Ni(en)(2)](4)[Fe(CN)(5)NO](2)[Fe(CN)(6)]center dot 6H(2)O

Authors
Gu, ZZ Sato, O Einaga, Y Kai, M Iyoda, T Fujishima, A Hashimoto, K
Citation
Zz. Gu et al., Crystal structure and photo-reaction of a new coordination polymer: [Ni(en)(2)](4)[Fe(CN)(5)NO](2)[Fe(CN)(6)]center dot 6H(2)O, B CHEM S J, 74(9), 2001, pp. 1617-1622
Citations number
23
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
74
Issue
9
Year of publication
2001
Pages
1617 - 1622
Database
ISI
SICI code
0009-2673(200109)74:9<1617:CSAPOA>2.0.ZU;2-Z
Abstract
A new photo-responsive coordination polymer of [Ni(en)(2)](4)[Fe(CN)(5)NO]( 2)[Fe(CN)(6)]. 6H(2)O was synthesized. In this compound, Ni-CN-Fe forms one -dimensional standing-wave-like chains, onto which photo-functional groups of pentacyanonitrosylferrate(II) are appended. Photo-irradiation with blue light at less than 200 K transformed the pentacyanonitrosylferrate(B) from the ground state to a metastable state, which could be reverted to the orig inal state by irradiation with red light.