The first observation of the [Cp3Mn](-) anion; structures of hexagonal [(eta(2)-Cp)(3)MnK center dot 1.5thf] and ion-separated [(eta(2)-Cp)(3)Mn](2)[Mg(thf)(6)]center dot 2thf

Authors
Bond, AD Layfield, RA MacAllister, JA McPartlin, M Rawson, JM Wright, DS
Citation
Ad. Bond et al., The first observation of the [Cp3Mn](-) anion; structures of hexagonal [(eta(2)-Cp)(3)MnK center dot 1.5thf] and ion-separated [(eta(2)-Cp)(3)Mn](2)[Mg(thf)(6)]center dot 2thf, CHEM COMMUN, (19), 2001, pp. 1956-1957
Citations number
33
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
19
Year of publication
2001
Pages
1956 - 1957
Database
ISI
SICI code
1359-7345(20011007):19<1956:TFOOT[>2.0.ZU;2-Q
Abstract
Hexagonal [(eta (2)-Cp)(3)MnK .1.5thf] 1 and ion-separated [(eta (2)-Cp)(3) Mn](2)[Mg(thf)(6)]. 2thf 2 are obtained from reactions of CpK and Cp2Mg, re spectively, with manganocene, Cp2Mn; they are the first complexes to be str ucturally characterised containing the [Cp3Mn](-) anion.