Ma. Reddy et al., Asymmetric synthesis of 2-azido-1-arylethanols from azido aryl ketone-beta-cyclodextrin complexes and sodium borohydride in water, CHEM COMMUN, (19), 2001, pp. 1974-1975
beta -Cyclodextrin catalyses for the first time the asymmetric reduction of
alpha -azido aryl ketones to corresponding alcohols of great significance
using sodium borohydride in water. The azido group appeared to be the best
fit among various groups studied. This asymmetric reduction using water as
solvent overcomes many of the drawbacks in the existing methodologies.